The study of lasing properties of rhodamine 6g in solutions of polymer-coated silver nanoparticles
Keywords:
polymer-coated silver nanoparticles, lasing characteristics, stimulated emission of the dye, threshold lasing,Abstract
We studied the lasing characteristics of Rhodamine 6G in the presence of polymer-coated silver nanoparticles. Synthesis of the polymer-coated silver nanoparticles was carried out in a aqueous alcohol solution. As the stabilizer and reducing agent the hydrophilic polymer poly-N-vinylpyrrolidone (PVP, SigmaAldrich) was used. The size of silver nanoparticles is equal to 40-50 nm. Stimulated emission of Rhodamine 6G molecules in aqueous alcohol solution of PVP with a concentration of dye equal to 10-3 mol/l was obtained in the long-wavelength fluorescence band upon photoexcitation with second harmonic of Nd:YAG laser gen= 532 nm, Еimp = 90 mJ, τ = 10 ns in the transversely form. Ascertained that the power density of the pump source 10 MW/cm2 observed lasing spectrum of the dye Rhodamine 6G in solution of PVP at a wavelength equal to λgen = 566 nm. When added to a solution of the dye-polymer-coated silver nanoparticles observed increase in intensity and a narrowing of the laser line. Furthermore, the presence of polymer-coated silver nanoparticles lowers the threshold level of generation.References
1 Maier S.A. Plasmonics: Fundamentals and Applications; Springer: Berlin/Heidelberg, Germany, 2007.
2 Annealed Silver–Island Films for Applications in Metal–Enhanced Fluorescence: Interpretation in Terms of Radiating Plasmons / K. Aslan [et al.] // J. of Fluorescence. – 2005. – Vol. 15, № 5. – P. 643–654.
3 Garoff S. et al. Electrodynamics at rough metal surfaces: photochemistry and luminescence of adsorbates near metal – island films // J. Chem. Phys. – 1984. – V. 81, № 11. – P.51895200.
4 Calander N. Surface plasmon–coupled emission and Fabry–Perot resonance in the sample layer: a theoretical approach // J. Phys. Chem. B. – 2005. – Vol. 109, № 29. – P. 13957–13963.
5 Protsenko I.E., Uskov A.V., Zaimidoroga O.A., Samoilov V.N., O'Reilly E.P., 2005, Dipole nanolaser, Phys. Rev. A, 71, 063812.
6 Noginov M.A., Zhu G., Drachev V.P., Shalaev V.M., 2007, Surface plasmon and gain media in Nanophotonics with Surface Plasmons, V.M. Shalaev and S.Kawata (Editors), 143-169.
7 Klimov V.V. Nanoplasmonics. – М.: Fizmatlit. 2009. – 480 p.
8 Drexhage K.H., Hansch T.W. et. al. Лазеры на красителях / под ред. Ф.П. Шефера. – М.: Мир, 1976. – 330 с.
2 Annealed Silver–Island Films for Applications in Metal–Enhanced Fluorescence: Interpretation in Terms of Radiating Plasmons / K. Aslan [et al.] // J. of Fluorescence. – 2005. – Vol. 15, № 5. – P. 643–654.
3 Garoff S. et al. Electrodynamics at rough metal surfaces: photochemistry and luminescence of adsorbates near metal – island films // J. Chem. Phys. – 1984. – V. 81, № 11. – P.51895200.
4 Calander N. Surface plasmon–coupled emission and Fabry–Perot resonance in the sample layer: a theoretical approach // J. Phys. Chem. B. – 2005. – Vol. 109, № 29. – P. 13957–13963.
5 Protsenko I.E., Uskov A.V., Zaimidoroga O.A., Samoilov V.N., O'Reilly E.P., 2005, Dipole nanolaser, Phys. Rev. A, 71, 063812.
6 Noginov M.A., Zhu G., Drachev V.P., Shalaev V.M., 2007, Surface plasmon and gain media in Nanophotonics with Surface Plasmons, V.M. Shalaev and S.Kawata (Editors), 143-169.
7 Klimov V.V. Nanoplasmonics. – М.: Fizmatlit. 2009. – 480 p.
8 Drexhage K.H., Hansch T.W. et. al. Лазеры на красителях / под ред. Ф.П. Шефера. – М.: Мир, 1976. – 330 с.
Downloads
How to Cite
Zeinidenov, A. K., Аimukhanov A. K., Ibrayev, N. K., & Kudaibergenov, S. E. (2014). The study of lasing properties of rhodamine 6g in solutions of polymer-coated silver nanoparticles. Recent Contributions to Physics (Rec.Contr.Phys.), 48(1), 36–43. Retrieved from https://bph.kaznu.kz/index.php/zhuzhu/article/view/26
Issue
Section
Condensed Matter Physics and Materials Science Problems. NanoScience