The raman spectroscopy, photoluminescence and photocatalytic activity of the zinc tungstate
91 60
Keywords:
hydrothermal synthesis, zinc tungstate, photoluminescence, photocatalytic activity, Raman spectroscopyAbstract
In this paper, the result of obtaining powder tungstate ZnWO4 is presented. Powders were prepared by two methods: the hydrothermal synthesis at a temperature of about 95°C at atmospheric pressure followed by heat treatment and powder synthesis in autoclave at a temperature of 180°C and at pressure above atmospheric. The structural features of the synthesized powders were studied, the Raman spectra and photoluminescence spectra, photocatalytic properties of the ZnWO4 obtained after synthesis and subsequent annealing in air were studied. There are relation between morphology and properties of the samples with the technological conditions of synthesis and subsequent annealing temperature. To obtain the polycrystalline phase of ZnWO4 at synthesis at 95°C was required additional annealing up to 500-600°C, while the synthesis at 180°C leads to the production of a polycrystalline ZnWO4 phase. A significant photocatalytic activity of synthesized materials in the decomposition of the test substance under the rhodamine lighting.
References
1. Tasbihi M., Bendyna J.K., Notten P.H.L., Hintzen H.T. (Bert). A Short Review on Photocatalytic Degradation of Formaldehyde // Journal of Nanoscience and Nanotechnology – 2015. – Vol. 15.– P.6386–6396.
2. Gayaa U.I., Abdullah A.H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems // Journal of Photochemistry and Photobiology C: Photochemistry Reviews. 2008. – Vol.9 – p. 1–12.
3. Bhatkhande D.S., Pangarkar V.G., Beenackers A.A.C.M. Photocatalytic degradation for environmental applications – a review //Journal of Chemical Technology and Biotechnology. – 2002. – Vol.77. - P. 102 – 116.
4. Jo W.‐K., Tayade R.J. Recent developments in photocatalytic dye degradation upon irradiation with energy‐efficient light emitting diode // Chinese Journal of Catalysis. – 2014. – Vol.35. - Р.1781–1792.
5. Rochkind M., Pasternak S., Paz Y. Using Dyes for Evaluating Photocatalytic Properties: A Critical Review // Molecules. – 2015. – Vol.20. – Р. 88-110.
6. Kraus H., Mikhailik V.B., Ramaches Y., Day D., Hutton K.B., Telfer J. Feasibility study of a ZnWO4 scintillator for exploiting materials signature in cryogenic WIMP dark mater searches // Phys. Lett. B. - 2005. – Vol.610. - Р.37-44.
7. Zhang L., Wang Z., Wang L., Zhang Y. “reparation of graphene/ZnWO4 composites and its electrochemical properties for lithium –ion batteries // Material Letters. – 2013. – P. 9-12.
8. Huang G., Zhang C., Zhu Y. “nWO4 photocatalyst with high activity for degradation of organic contaminants”// Journal of Alloys and Compounds. – 2007. – Vol. 432. – P. 269–276.
9. Siriwong P., Thongtem T., Phuruangrat A., Thongtem S. Hydrothermal synthesis, characterization, and optical properties of wolframite ZnWO4 nanorods // CrystEngComm. – 2011. – Vol.13. – P.1564–1569.
10. Brik M.G., Nagirnyi V., Kirm M. A-initio studies of electronic and optical properties of ZnWO4 and CaWO4 single crystals // Materials chemistry and physics. – 2012. – Vol.134. – P. 1113-1120.
11. Perakis A., Sarantopoulou E., Raptis C. Pressure and temperature dependent raman study of ZnWO4 // High Pressure Research. – 2000. – Vol. 18. –P. 181-187.
12. Mikhailik V.B., Kraus H., Miller G., Mykhaylyk M.S., Wahl D. Luminescence of CaWO4, CaMO4 and ZnWO4 crystals under different excitations // Journal of applied physics. – 2015. – Vol.77. – P.083523(8).
13. Лисицын В.М., Карипбаев Ж.Т., Лисицына Л.А., Тупицына И.А., Купчишин А.И. Фотолюминесценция кристаллов вольфрамата цинка, подвергнутых термической обработке в атмосфере кислорода и водорода // Известия вузов. Физика. – 2014. – №9/3. – C.132-136;
14. Gao B., Fan H., Zhang X., Song L. Template – free hydrothermal synthesis and high photocatalytic activity of ZnWO4 nanrods // Materialscience and engineering B. – 2012. – Vol.177. – Р.1126-1132.
References
1. M. Tasbihi, J.K. Bendyna, P.H.L. Notten, H.T. (Bert) Hintzen, Journal of Nanoscience and Nanotechnology, 15, 6386–6396, (2015).
2. U.I. Gayaa, A.H. Abdullah, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 9, 1–12, (2008).
3. D.S. Bhatkhande, V.G. Pangarkar, A.A.C.M. Beenackers, Journal of Chemical Technology and Biotechnology, 77, 102-116, (2002).
4. W.‐K. Jo, R.J. Tayade, Chinese Journal of Catalysis, 35, 1781–1792, (2014).
5. M. Rochkind, S. Pasternak, Y. Paz, Molecules, 20, 88-110, (2015).
6. H. Kraus, V.B. Mikhailik, Y. Ramaches, D. Day, K.B. Hutton, J. Telfer, Phys. Lett. B, 610- 37-44, (2005).
7. L. Zhang, Z. Wang, L. Wang, Y. Zhang, Material Letters, 9-12, (2013).
8. G. Huang, C. Zhang, Y. Zhu, Journal of Alloys and Compounds, 432, 269–276, (2007).
9. P. Siriwong, T. Thongtem, A. Phuruangrat, S. Thongtem, CrystEngComm., 13, 1564–1569, (2011).
10. M.G. Brik, V. Nagirnyi, M. Kirm, Materials chemistry and physics, 134, 1113-1120, (2012).
11. A. Perakis, E. Sarantopoulou, C. Raptis, High Pressure Research, 18, 181-187, (2000).
12. V.B Mikhailik, H. Kraus., G. Miller., M.S Mykhaylyk., D. Wahl, Journal of applied physics 97, 083523(8), (2015).
13. V.M. Lisitsyn, ZH.T. Karipbayev, L.A. Lisitsyna, I.A. Tupitsyna, A.I. Kupchishin, Izvestiya vuzov. Fizika, 9(3), 132-136, (2014). (in russ).
14. B. Gao, H. Fan, X. Zhang, L. Song, Materialscience and engineering B 177, 1126-1132, (2012).
2. Gayaa U.I., Abdullah A.H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems // Journal of Photochemistry and Photobiology C: Photochemistry Reviews. 2008. – Vol.9 – p. 1–12.
3. Bhatkhande D.S., Pangarkar V.G., Beenackers A.A.C.M. Photocatalytic degradation for environmental applications – a review //Journal of Chemical Technology and Biotechnology. – 2002. – Vol.77. - P. 102 – 116.
4. Jo W.‐K., Tayade R.J. Recent developments in photocatalytic dye degradation upon irradiation with energy‐efficient light emitting diode // Chinese Journal of Catalysis. – 2014. – Vol.35. - Р.1781–1792.
5. Rochkind M., Pasternak S., Paz Y. Using Dyes for Evaluating Photocatalytic Properties: A Critical Review // Molecules. – 2015. – Vol.20. – Р. 88-110.
6. Kraus H., Mikhailik V.B., Ramaches Y., Day D., Hutton K.B., Telfer J. Feasibility study of a ZnWO4 scintillator for exploiting materials signature in cryogenic WIMP dark mater searches // Phys. Lett. B. - 2005. – Vol.610. - Р.37-44.
7. Zhang L., Wang Z., Wang L., Zhang Y. “reparation of graphene/ZnWO4 composites and its electrochemical properties for lithium –ion batteries // Material Letters. – 2013. – P. 9-12.
8. Huang G., Zhang C., Zhu Y. “nWO4 photocatalyst with high activity for degradation of organic contaminants”// Journal of Alloys and Compounds. – 2007. – Vol. 432. – P. 269–276.
9. Siriwong P., Thongtem T., Phuruangrat A., Thongtem S. Hydrothermal synthesis, characterization, and optical properties of wolframite ZnWO4 nanorods // CrystEngComm. – 2011. – Vol.13. – P.1564–1569.
10. Brik M.G., Nagirnyi V., Kirm M. A-initio studies of electronic and optical properties of ZnWO4 and CaWO4 single crystals // Materials chemistry and physics. – 2012. – Vol.134. – P. 1113-1120.
11. Perakis A., Sarantopoulou E., Raptis C. Pressure and temperature dependent raman study of ZnWO4 // High Pressure Research. – 2000. – Vol. 18. –P. 181-187.
12. Mikhailik V.B., Kraus H., Miller G., Mykhaylyk M.S., Wahl D. Luminescence of CaWO4, CaMO4 and ZnWO4 crystals under different excitations // Journal of applied physics. – 2015. – Vol.77. – P.083523(8).
13. Лисицын В.М., Карипбаев Ж.Т., Лисицына Л.А., Тупицына И.А., Купчишин А.И. Фотолюминесценция кристаллов вольфрамата цинка, подвергнутых термической обработке в атмосфере кислорода и водорода // Известия вузов. Физика. – 2014. – №9/3. – C.132-136;
14. Gao B., Fan H., Zhang X., Song L. Template – free hydrothermal synthesis and high photocatalytic activity of ZnWO4 nanrods // Materialscience and engineering B. – 2012. – Vol.177. – Р.1126-1132.
References
1. M. Tasbihi, J.K. Bendyna, P.H.L. Notten, H.T. (Bert) Hintzen, Journal of Nanoscience and Nanotechnology, 15, 6386–6396, (2015).
2. U.I. Gayaa, A.H. Abdullah, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 9, 1–12, (2008).
3. D.S. Bhatkhande, V.G. Pangarkar, A.A.C.M. Beenackers, Journal of Chemical Technology and Biotechnology, 77, 102-116, (2002).
4. W.‐K. Jo, R.J. Tayade, Chinese Journal of Catalysis, 35, 1781–1792, (2014).
5. M. Rochkind, S. Pasternak, Y. Paz, Molecules, 20, 88-110, (2015).
6. H. Kraus, V.B. Mikhailik, Y. Ramaches, D. Day, K.B. Hutton, J. Telfer, Phys. Lett. B, 610- 37-44, (2005).
7. L. Zhang, Z. Wang, L. Wang, Y. Zhang, Material Letters, 9-12, (2013).
8. G. Huang, C. Zhang, Y. Zhu, Journal of Alloys and Compounds, 432, 269–276, (2007).
9. P. Siriwong, T. Thongtem, A. Phuruangrat, S. Thongtem, CrystEngComm., 13, 1564–1569, (2011).
10. M.G. Brik, V. Nagirnyi, M. Kirm, Materials chemistry and physics, 134, 1113-1120, (2012).
11. A. Perakis, E. Sarantopoulou, C. Raptis, High Pressure Research, 18, 181-187, (2000).
12. V.B Mikhailik, H. Kraus., G. Miller., M.S Mykhaylyk., D. Wahl, Journal of applied physics 97, 083523(8), (2015).
13. V.M. Lisitsyn, ZH.T. Karipbayev, L.A. Lisitsyna, I.A. Tupitsyna, A.I. Kupchishin, Izvestiya vuzov. Fizika, 9(3), 132-136, (2014). (in russ).
14. B. Gao, H. Fan, X. Zhang, L. Song, Materialscience and engineering B 177, 1126-1132, (2012).
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How to Cite
Marhabaeva, A., Abdullin, K., Lisitsyn, V., & Nemkaeva, R. (2018). The raman spectroscopy, photoluminescence and photocatalytic activity of the zinc tungstate. Recent Contributions to Physics (Rec.Contr.Phys.), 60(1), 72–81. Retrieved from https://bph.kaznu.kz/index.php/zhuzhu/article/view/515
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Condensed Matter Physics and Materials Science Problems. NanoScience
