Preparation, characterization and catalytic activity of gold nanoparticles stabilized by poly (n-vinylpyrrolidone) and poly (N,N-dimethyl-N,N-diallylammonium chloride)

Authors

  • E.K. Baigaziyeva Abay Kazakh National Pedagogical University, Almaty, Kazakhstan
  • K. Schuette Heinrich Heine university, Dusseldorf, Germany
  • G.S. Tatykhanova K.I. Satpaev Kazakh national technical university, Almaty, Kazakhstan
  • C. Janiak Heinrich Heine university, Dusseldorf, Germany
  • S.E. Kudaibergenov Institute of polymer materials and technology, Almaty, Kazakhstan
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Keywords:

colloidal gold nanoparticles, optical properties, structure, morphology

Abstract

Optical properties, structure and morphology of colloidal gold nanoparticles (AuNPs) stabilized by poly (N-vinylpyrrolidone) (PVP) and poly(N,N-dimethyl-N,N-diallylammonium chloride) (PDMDAAC) were characterized by visible spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The influence of the molecular weight (Mw) of PVP on the size of AuNPs was studied. The catalytic activity of polymer-protected AuNPs with respect to hydrogenation of p-nitrophenol was studied. High conversion degree of 4-nitrophenol to 4-aminophenol was found.

References

1 Bekturov E.A., Kudaibergenov S.E., Iskakov R.M., Zharmagambetova A.K., Ibraeva Zh.E., Shmakov S. Polymer-protected nanoparticles of metals. – Almaty: S-Print, 2010.

2 Shen J., Tenhu H. Recent advances in polymer protected gold nanoparticles: Synthesis, properties and applications // Chemical Communications. – 2007. – Is. 44. - P.4580-4598.

3 Andrea B. R. Mayer, James E. Mark. Colloidal gold nanoparticles protected by water-soluble homopolymers and random copolymers // European Polymer Journal. – 1998. - Vol.34. - P.103-108.

4 Didier Astruc. Nanoparticles and Catalysis. - Willey-VCH, Weinheim, 2008.

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How to Cite

Baigaziyeva, E., Schuette, K., Tatykhanova, G., Janiak, C., & Kudaibergenov, S. (2012). Preparation, characterization and catalytic activity of gold nanoparticles stabilized by poly (n-vinylpyrrolidone) and poly (N,N-dimethyl-N,N-diallylammonium chloride). Recent Contributions to Physics (Rec.Contr.Phys.), 42(3), 63–67. Retrieved from https://bph.kaznu.kz/index.php/zhuzhu/article/view/710

Issue

Vol. 42 No. 3 (2012): KazNU Bulletin. Physics series

Section

Condensed Matter Physics and Materials Science Problems. NanoScience