Effect of pseudorotation on isochoric thermal conductivity of hydrocarbons in disordered phases

Authors

  • V.V. Sagan B. Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine, 47 Lenin Ave., 61103 Kharkov, Ukraine
  • V.A. Konstantinov B. Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine, 47 Lenin Ave., 61103 Kharkov, Ukraine
  • V.P. Revyakin B. Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine, 47 Lenin Ave., 61103 Kharkov, Ukraine
  • A.V. Karachevtseva B. Verkin Institute for Low Temperature Physics and Engineering of NAS of Ukraine, 47 Lenin Ave., 61103 Kharkov, Ukraine
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Keywords:

isochoric thermal conductivity, hydrocarbon compounds, translation-orientation movement

Abstract

The isochoric thermal conductivity of solid five-membered heterocyclic compounds has been measured in orientationally ordered and orientationally disordered («plastic») phases on samples of different density in a wide interval of temperatures and pressures. The objects were: furan – C4H4O, cyclopentane – C5H10, thiophene – C4H4S. The aim of this research was to study the influence of the translation-orientational
motion on the behavior of the isochoric thermal conductivity and to estimate the possible contribution of  pseudorotation to the total heat transfer.

References

1 V.A. Konstantinov, Heat transfer in molecular crystals, In: Aziz Belmiloudi (Eds.), Heat Transfer – Theoretical Analysis, Experimental Investigations and Industrial Systems, «InTech» Open Access Publisher (2011).

2 D.G. Cahill, S.K. Watson, and R.O. Pohl, Phys. Rev. B 46, 6131 (1992).

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How to Cite

Sagan, V., Konstantinov, V., Revyakin, V., & Karachevtseva, A. (2015). Effect of pseudorotation on isochoric thermal conductivity of hydrocarbons in disordered phases. Recent Contributions to Physics (Rec.Contr.Phys.), 50(3), 17–18. Retrieved from https://bph.kaznu.kz/index.php/zhuzhu/article/view/798

Issue

Vol. 50 No. 3 (2014): KazNU Bulletin. Physics series

Section

Condensed Matter Physics and Materials Science Problems. NanoScience