Antireflection сoatings for silicon solar cells formed by wet chemistry methods
Keywords:
porous silicon, solar cells, nanowires, antireflection.Abstract
The results of theoretical and experimental investigations of nanostructured silicon-based layers of different morphology and consideration of their application as antireflection coatings for silicon solar cells are presented. Nanostructured silicon layers were obtained by three wet chemistry methods: (1) electrochemical etching in hydrofluoric acid solutions (porous silicon formation); (2) electrochemical stain etching in hydrofluoric and nitric acids and (3) metal-assisted chemical etching. The obtained porous layers exhibit optical properties of semiconductor nanostructures with sizes in the range from 1 up to 100 nm. The minimal total reflection coefficient below 1% in the spectral range from 400 to 1100 nm was obtained for the coatings based on Si layers formed by metal-assisted chemical etching
References
2 Yerokhov V., Melnyk I., Tsisaruk A. and Semochko I. Porous silicon in solar cell structures. //OptoElectronics Review. – 2000. – Vol. 8. – No. 4. – P. 414-417.
3 Fauchet P. Porous Polycrystalline Silicon Thin Film Solar Cells // Final Report of National Renewable Energy Laboratory, -2003, NREL/SR-520-34824. -20 p.
4 Huang Zh., Geyer N., Werner P., J. de Boor and Goesele U. Metal-Assisted Chemical Etching of Silicon: A Review.// Adv. Materials. -2011, –V 23. – P.285-308.
5 Sivakov V., Andra G., Gawlik A., Berger A., Plentz J., Falk F. and Christiansen S.H. Silicon NanowireBased Solar Cells on Glass: Synthesis, Optical Properties and Cell Parameters.// Nano Letters, -2009, -Vol.9,
-№4. – P. 1549-1554.
6 Bisi O., Ossicini S., and Pavesi L. Porous silicon: a quantum sponge structure for silicon based optoelectronics // Surf. Sci. Rep. -2000, – V. 38. – No1. – 126 p.
7 Lehmann V., Stengl R., Luigart A. On the morphology and the electrochemical formation mechanism of mesoporous silicon // Materials Scienceand Engineering B. -2000, V.69–70. – P.11-22.
8 Luca Boarino et al. Macro and quasi-mesoporous silicon by self-assembling and metal assisted etching.// Phys.Status Solidi A. -2011, -V. 208. – No.6. – P.1412–1416.